Esposito Research Group Blog

Esposito Research Group Blog

Category Archives: scientific journal article

“The Grid’s Great Balancing act”^ – status in California and China

29 Thursday Jun 2017

Posted by danesposito in energy, energy storage, scientific journal article, solar fuels, Solar-Popular Press, Uncategorized

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california, china, curtailment, electricity, electrolysis, grid, negative prices, solar

It’s no secret that there will be significant challenges to achieving a clean energy future where a large percentage of society’s energy comes from renewable resources such as solar and wind.  Many of these challenges relate to the fact that solar and wind are variable and sometimes intermittent generators– they only produce electricity when the sun is shining and the wind is blowing.  Thus, the amount of electricity supplied by these resources is often out of sync with the demand for electricity, an issue that gets worse as solar and wind achieves a larger percentage of a region’s generating capacity. In order to deal with the imbalance with supply and demand, a combination of three actions are often taken:

  1. The price of electricity decreased. Sometimes, electricity prices can even go negative, with a state like CA having excess electricity paying states like Arizona to take the extra electricity off their grid (see article below).
  2. Conventional power plants, such as natural gas plants, are turned off/on to help balance demand and supply.
  3. Excess electricity from solar and/or wind is curtailed, meaning the connection between the solar panel or wind turbine and the grid is cut, and the electricity is wasted. (free electricity!).

In California, where almost 14% of its electricity was obtained from solar in 2016, this grid balancing act is already becoming extremely challenging, as discussed in a recent LA Times article that provides a lot of useful stats and discussion:

http://www.latimes.com/projects/la-fi-electricity-solar/

In China, which is the world leader in solar panel production and increasingly installing large amounts of solar power plants itself, the imbalance between electricity supply and demand is become especially acute in provinces where transmission of electricity to the large population centers is highly inadequate.  According to the article below, curtailment rates of solar-generated electricity are often 30% or higher!:

http://www.bbc.com/news/business-40341833

While improvements to the grid (e.g. smart grid technologies) and demand-side management can go a long way to help alleviate some of the issues involved with balancing electricity supply and demand, there is a limit to how much they can help—especially in a future where solar and wind generate 50% or more of a region’s electricity.  In this case, many studies agree that low-cost and scalable energy storage technologies are crucially important.   Batteries are one option, and have the benefit of high round trip efficiencies, but electrolyzer technologies that convert electricity into storable chemical fuels are another option.   Electricity-to-fuel technologies such as the ones we work on in our lab also represent a huge opportunity because fuels can be used for many energy applications and sectors that are not currently very reliant on electricity.  The flexibility and storability of fuels thus make them highly attractive 1.) for their ability to utilize low-cost or free electricity, and 2.) their ability to impact many different energy use sectors (transportation, industrial/chemical, agriculture, commercial) that are predominantly reliant on fossil-fuels at this time.

^credit: the term “The grid’s great balancing act” has been often used by Prof. Cory Budischak at Delaware Technical Community College. A more detailed analysis of a future scenario in which  99.9% of the electricity is provided by solar and wind can be found in a paper that he published a few years ago in J. Power Sources:

http://www.sciencedirect.com/science/article/pii/S0378775312014759

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In situ Measurement of Sub-particle reaction rates of TiO2 nanorod photoanodes

13 Monday Jun 2016

Posted by danesposito in scientific journal article, solar fuels, Uncategorized

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in situ measurements, photoelectrochemistry, TiO2

A nice study was recently published in Nature on the use of super-resolution fluorescence-based imaging and scanning photocurrent microscopy to study sub-particle reaction rates on TiO2 nanorods:

http://www.nature.com/nature/journal/v530/n7588/abs/nature16534.html

very neat measurements!

Technoeconomic analysis on solar hydrogen production

31 Tuesday May 2016

Posted by JackDavis in energy, Hydrogen Economy, scientific journal article, solar fuels

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economics, energy, hydrogen, photovoltaics, solar

A technoeconomic analysis on solar hydrogen production was recently published in Energy. Environ. Sci. by Shaner, et al. (Energy. Environ. Sci., 2016, Advance Article). The levelized cost of hydrogen was compared between photovoltaic-electrolyzers (PV-E), photoelectrochemical cells (PECs), and fossil fuel derived hydrogen using steam methane reforming (SMR).

This paper highlights the strengths of PEC systems and outlines the challenges which must be met in order for the technology to become viable. One way to make solar hydrogen production competitive with SMR is to tax the carbon dioxide that is produced. They estimate that for the current PEC technology to achieve hydrogen price parity with SMR, a carbon tax of $1000/ton C02 is required. If a solar concentrator PEC is used, the estimated tax decreases to $800/ton CO2.

 

a-Si multi-junction solar cells

05 Friday Jun 2015

Posted by danesposito in scientific journal article, Solar-Popular Press

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amorphous silicon, microcrystalline silicon, multi-junction solar cells, Silicon, solar, water splitting

Researchers in Japan recently reported a triple-junction amorphous Si solar cell with a stabilized efficiency of 13.6%, a world record for triple junction thin film Si solar cells:

http://scitation.aip.org/docserver/fulltext/aip/journal/apl/106/21/1.4921794.pdf?expires=1433502759&id=id&accname=guest&checksum=F3214C32C4C1870006DE29D99DCA89B0

This triple junction solar cell is comprised of one a-Si cell, and two microcrystalline Si cells (uc-Si), whereas many triple junction a-Si cells demonstrated in the past have made use of amorphous silicon germanium (a:SiGe:H). A key reason these researchers were able to achieve the record stabilized efficiency is because the triple junction device was “current limited” by one of the uc-Si cells, which can exhibit very little initial performance degradation due to the Staebler-Wronski effect, which can significantly decrease the efficiency of amorphous Si solar cells.

The triple junction solar cell achieves a Vmpp of 1.58 V and Jmpp of 9 mA; a pretty good match for water splitting!

Here is an additional write-up from Phys.org:

http://phys.org/news/2015-06-solar-cell-world-stabilized-efficiency.html

February Journal club article

04 Wednesday Feb 2015

Posted by danesposito in scientific journal article

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hydrogen, silicon photoelectrochemistry, solar fuels

nature communications paper on MIS photocathode with STO insulator:

Schematic structure, band alignment and STO-thickness-dependent performance.

http://www.nature.com/nnano/journal/v10/n1/full/nnano.2014.277.html

Back-Illuminated Photoelectrodes

29 Monday Dec 2014

Posted by danesposito in scientific journal article

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back-illumination, Silicon, solar fuels

A recent publication in Energy & Environmental Science out of the Technical University of Denmark investigates the use of back-illuminated Silicon-based photocathodes for photoelectrochemical cells:

http://pubs.rsc.org/en/Content/ArticleLanding/2014/EE/C4EE03723E#!divAbstract

Many photoelectrochemical reactor/cell designs based on tandem (2 absorber) stacks employ Si as the bottom component, meaning that light will first pass through the back contact of this cell rather than the front surface where the electrochemical reaction is taking place.

Despite the practical necessity of back illumination in many PEC device designs, back illumination brings with it several challenges, including lower current density due to bulk recombination and complications associated with using a transparent conducting back contact.

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